Continuing their attempt to make sure that you can play The Elder Scrolls V: Skyrim on everything available on the market, Sony has shown a trailer at their E3 conference demonstrating that you will eventually be able to play the best-selling high fantasy open world RPG on PlayStation VR.
For all intents and purposes, it appears as though the VR version of Skyrim will play like the normal versions of Skyrim, just with motion controls (and all the drawbacks and benefits that are associated with motion controls), presumably making combat slightly more immersive and or dangerous to your furniture.
It may also be a safe bet to assume that Sony's policy on mods is unchanged for the PlayStation VR version of Skyrim.